INTRODUCTION
Then, as the onslaught of high performance tooling demanded tighter and tighter tolerances manifestation of words such as scoring and galling became more reason to take advantage of hard chrome's intrinsic physical properties: anti galling low coefficient of friction; anti-fretting and anti-spalling.
Finally, with the advent of highly corrosive and highly erosive materials coupled with both optical and aesthetic quality requirements, the need for properties such as only chrome can offer have become the everyday talk of not only the mold maker, but the mold designer & the molder as well.
DISCUSSION
The hardness alone would not be sufficient to secure widespread use in plastics tooling applications, because a number of other hard materials and other hardening processes are available. It is the combination of very great hardness with extremely good corrosion resistance (equal or superior under most conditions to that of such noble metals as gold or platinum), and very low coefficient of friction or unique surface qualities which gives such remarkable results in plastics tooling applications of hard chrome. To this should be added the ease of stripping and replating for repeated salvage where the plate wears beyond permissible limits.
The benefits of the hardness of chrome deposits is not effectively obtained unless the coating is deposited on a sufficiently hard basis metal, and to a satisfactory thickness. Even a relatively heavy deposit of hard chrome may be crushed or indented on a soft metal such as copper or aluminum. The best possible adhesion is also important in many uses where the surface may be subjected to severe stress and shock Both conditions being prevalent in the molding cycle.
The low coefficient of friction and desirable surface properties of chromium are realized for the most part only on relatively smooth surfaces. The deposits can be ground and lapped to size.
The deposits are easily ground but are sensitive to the heat generated and should be ground with very light cuts, soft wheel & plenty of coolant.
In most cases bright deposits are obtained on highly polished molding surfaces, with no further mechanical treatment required. By means of careful operation it is possible to plate to size within very close limits.
Overall the mold designer, mold maker, and molder have at their disposal a unique combination of physical properties, which for the most part offer some level solution for the most common of plastics tooling problems. How does one, then, determine when, where, and how much.
APPLICATION BEFORE THE PROBLEMS
However, .0002 in. of hard chrome on a mirror finished core (especially a large core) can save hundreds if not thousands of dollars in production just by preventing oxidation from forming on a sweating mold. It won't appreciably affect any dimensions; if maintenance forgets to oil it down before storage, it won't rust; and with today's methods of plating adhesion qualities (from qualified sources) are approaching perfection. Now why doesn't the mold designer know this? Because, to the average mold designer hard chrome means someone made a mistake: salvage.
Again: .0002 in. of dense hard chrome on a large L/D ratio core, with minimum draft can make enough difference in friction reduction that the core without chrome may never eject acceptability.
A great many of the plastics tooling applications of hard chrome are derive from the fact that the deposit has a very low surface energy, and because of the very low coefficient of friction it is ideally suitable for many engineering applications.
These are just two cases in which a very thin deposit could make a world of difference. The total list, on the other hand, can be endless. The application mostly fall in the same general categories, specifically abrasion resistance, corrosion resistance and friction reduction.
In order for the mold designer or mold maker to effectively specify and successfully benefit from the various properties of chrome, he must first of all accept it. In order for this to be a success, somewhat of a crash course is in order!
PROPERTIES OF HARD CHROME
Some of the characteristics of chrome in the metallic state are as follows:
Atomic Weight 52.01
Melting Point 3362 F°
Crystal Form Body Centered cubic (bcc)
Deposits of hard chrome have a hard lustrous appearance, the deposit is not affected by heat up to 800° F to any great extent, and it resists corrosion extremely well, and is attacked by few chemicals or substances.
The main properties for which it is applied are:
HARDNESS AND RESISTANCE TO WEAR
850 -1000 Vickers P.N.
70 Rockwell C
800 Brinell
The resistance to wear of hard chrome is based essentially on this hardness and also on the fact that the deposited metal has a low surface energy. Unfortunately it is very difficult to lay down specific means of testing and measuring wear, although it is a definite fact the hard chrome performs in a superior manner under most conditions.
In plastic tooling applications the main sources of wear met with, under conditions of:
The protective qualities of the deposit depend on a number of factors, the most important of which are the fine grain structure of the deposited metal, its resistance to oxidizing and reducing agents and very high temperatures which are necessary to oxidize the metal.
Unfortunately one inorganic acid gas, which results commonly from the degradation of PVC, is beyond the resistance of the plate. Usage in such an application should be very limited with at least .003 deposit.
In plastics tooling applications, heat is hardly a factor to consider as possibly affecting the chrome properties. Hard chrome resists the effects of heat well up to 800° and then only changes slightly up to 1000° F.
RECOMMENDED THICKNESS
LOW COEFFICIENT OF FRICTION
Chrome on white metal .16
Chrome on steel .19 Static coefficient
Steel on white metal .26 of friction
Steel on steel .31
White metal on white metal .55
It is also a fact that chrome can be ground or polished to a high finish. This is a great advantage in applications where the minimum of draft is mandatory hard chrome prevents sticking thereby reducing the amount of deformation upon ejection of the molded part.
The approach in the aforementioned uses should be such that final mirror finish polishing is accomplished on the plated surface, so as to avoid repetition of labor.
APPLICATIONS OF HARD CHROME
The following list is given as a guide for the successful use of the deposit in the more established applications.
SUMMARY
Yet like any revolution it is subject to mistakes by, or often disaster for, those who are overcome by the thrill of new horizons but are blind or careless to its pursuit.
No longer should hard chrome be an ugly word to the mold designer, mold maker, or molder.
Faced with the ever rising cost of labor plus a need for increased profits, the applications of hard chrome for both salvage and performance requirements must be developed and concerned with design and engineering.
The designer of tomorrow's molds must realize that the benefits of hard chrome must not be overlooked. They must be incorporated in the initial plans where problems in processing are anticipated. However, the designer must be aware of specification, as well. Just to say "flash chrome" will no longer suffice, or as one might have it, will continue to bring about the same results.
Hard chrome applications in the engineering discipline are by far no new toy. It is almost now sixty years since deposition was offered to the engineering industry deposition was offered to the engineering industry, and during this time the importance of the process has steadily increased.
The application of hard chrome is now a recognized means of prolonging the life of all types of metal parts subject to corrosion, friction and abrasion. And it should be well borne by the mold designer, mold maker and molder that they will benefit by learning a little more about the practical side of the job. There is no doubt that very many applications have reached a point where hard chrome has become an indispensable tool.
END